Alum ~ Potassium Aluminium Sulphate
Chemical formula: KAl(SO4)2 (often used as the hydrated form, KAl(SO4)2.12H2O)
Effect on colour: Alum is the most commonly used mordant in Indian textile dyeing and has been for thousands of years. It brightens and clarifies colour, producing clear, warm, luminous tones. With madder, alum produces the classic Indian red ~ warm, rich, and enduring. With pomegranate rind, alum gives a clear golden yellow. With lac, alum produces vivid crimson.
Properties: Alum is relatively non-toxic, water-soluble, and widely available. It does not significantly alter the hand (feel) of the fabric. It is the safest and most commonly used mordant across all natural dye traditions worldwide.
In Indian practice: Alum is ground to a paste, mixed with gum arabic or another thickening agent, and applied to the fabric through block printing. The printed mordant paste is invisible or near-invisible on the cloth. When the mordanted fabric is subsequently immersed in a dye bath, only the areas where alum was printed absorb and permanently fix the dye. This is the basis of the entire mordant-printing tradition ~ the ability to produce coloured patterns on white ground using a single dye bath.
Indian name: "Phitkari" (Hindi)
Iron ~ Ferrous Sulphate & Iron Acetate
Chemical forms: Ferrous sulphate (FeSO4), iron acetate (Fe(CH3COO)2 ~ the traditional "kas" or "kasim" made by fermenting iron in jaggery water)
Effect on colour: Iron is a "saddening" mordant ~ it darkens and deepens colour, pulling warm tones toward cool, sombre shades. With madder, iron produces deep purple-black instead of red. With pomegranate rind, iron gives olive green instead of gold. With tannin-rich fabrics (pre-treated with myrobalan), iron alone produces a deep, permanent black.
Properties: Iron is one of the most powerful mordants available. Even in small quantities, it has a dramatic effect on colour. However, iron can weaken cellulose fibres over time ~ the iron ions catalyse the degradation of cotton, a process known as "tendering." This is why iron-printed areas of very old Indian textiles are sometimes the first to deteriorate.
In Indian practice: Iron is the second great mordant of the Indian printing tradition. The classic two-colour Indian block print ~ red and black on white ~ is achieved entirely through the selective application of alum and iron mordants, followed by a single madder dye bath. The alum-printed areas turn red; the iron-printed areas turn black; the unmordanted ground remains white.
Traditional preparation: The traditional "kas" of Rajasthan is made by soaking scrap iron (horseshoe nails, iron filings) in a mixture of jaggery and water for two to three weeks. The organic acids from the fermenting jaggery dissolve the iron, producing iron acetate ~ a dark, pungent liquid that is then filtered and mixed into a printing paste.